THE PHOTOCHEMISTRY OF THE ALIPHATIC NITROCOMPOUNDS .9. THE FLASH-PHOTOLYSIS OF THE ALPHA-POLYNITROALKYLSULFIDES AND ALPHA-POLYNITROALKYLSULFONES

被引：0
|
作者：
MAKSYUTOV, EM
SLOVETSKII, VI
机构：
[1] N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 07期
关键词：
D O I：
10.1007/BF00947303
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1. The photochemical breakdown of the α-polynitroalkylsulfides (I) and α-polynitroalkylsulfones (II) proceeds largely through homolytic {Mathematical expression} bond rupture with the formation of radicals. 2. The extent of breakdown of (I) and (II) is determined by the molecular structure, being almost completely unaffected by the nature of the solvent. The ratio of the final photolysis products is determined by secondary reactions between the radicals and between the radicals and the solvent. © 1980 Plenum Publishing Corporation.
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页码：1387 / 1391
页数：5
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