MAGNETIC EFFECTS IN THE REACTION OF BENZYL-CHLORIDE WITH TRIETHYLGERMYL DERIVATIVES OF ALKALI-METALS

被引：4

作者：

LESHINA, TV ^{[1
]}

MARYASOVA, VI ^{[1
]}

SAGDEEV, RZ ^{[1
]}

MARGORSKAYA, OI ^{[1
]}

BRAVOZHIVOTOVSKII, DA ^{[1
]}

KRUGLAYA, OA ^{[1
]}

VYAZANKIN, NS ^{[1
]}

机构：

[1] ACAD SCI USSR,INST ORGAN CHEM,IRKUTSK,USSR

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1979年 / 12卷 / 04期

关键词：

D O I：

10.1007/BF02061760

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of benzyl chloride with triethylgermyllithium and its analogs have been studied by the1H-CIDNP method. A reaction mechanism is suggested. Benzyl and triethylgermyl free radicals have been found to be the precursors of main products. The magnetic field effects on the ratio of the main reaction products indicate that the radical path of their formation is predominant. The assumption is made that the ethylgermyl radicals take part in the reaction in the associated state. © 1979 Akadémiai Kiadó.

引用

页码：491 / 496

页数：6

共 8 条

[1]

BUCHACHENKO AL, 1978, MAGNETIC SPIN EFFECT, P54

[2]

Denisov E. T., 1971, RATE CONSTANTS HOMOL

[3]

Kochi J K, 1973, FREE RADICALS, V1

[4] EFFECTS OF MAGNETIC-FIELD ON CHEMICAL-REACTIONS [J].

SAGDEEV, RZ ;

MOLIN, YN ;

SALIKHOV, KM ;

LESHINA, TV ;

KAMHA, MA ;

SHEIN, SM .

ORGANIC MAGNETIC RESONANCE, 1973, 5 (12) :603-605

[5]

SAGDEEV RZ, 1972, IAN SSSR KH, P2128

[6]

SHAAF T, 1974, J AM CHEM SOC, V96, P7593

[7]

TALALAEVA TV, 1971, METHODS ORGANOELEMEN, V1, P28

[8]

VYAZANKIN NS, 1964, DOKL AKAD NAUK SSSR+, V158, P382

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