SPIN ORBITAL COUPLING AND THE ZEEMAN EFFECT IN MOLECULAR CRYSTALS

被引:20
作者
Castro, George [1 ]
Hochstrasser, Robin M.
机构
[1] Univ Penn, John Harrison Lab Chem, Philadelphia, PA 19104 USA
关键词
D O I
10.1016/0038-1098(65)90270-X
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A theory of Zeeman intensity patterns for singlet-triplet transitions in molecular crystals is presented and tested by experiments on single crystals of p-dibromobenzene at 4.2 degrees K. The results show that it is possible to make a direct measurement of which component of the spin-orbital interaction operator is most effective in obtaining intensity for the singlet-triplet transition.
引用
收藏
页码:425 / 428
页数:4
相关论文
共 6 条
[1]  
Bezzi S, 1942, GAZZETTA, VI, P318
[2]  
CASTRO G, J CHEM PHYS IN PRESS
[3]   SPIN-ORBIT INTERACTION IN AROMATIC MOLECULES [J].
MCCLURE, DS .
JOURNAL OF CHEMICAL PHYSICS, 1952, 20 (04) :682-686
[4]   ON THE MAGNETIC PROPERTIES OF COVALENT XY6 COMPLEXES [J].
STEVENS, KWH .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1953, 219 (1139) :542-555
[5]   THE VIBRATION FREQUENCIES OF THE SYMMETRICAL PARA-DIHALOGENOBENZENES [J].
STOJILJKOVIC, A ;
WHIFFEN, DH .
SPECTROCHIMICA ACTA, 1958, 12 (01) :47-56
[6]   VECTOR MODEL FOR SPIN-ORBIT INTERACTION IN POLYATOMIC MOLECULES [J].
WEISSMAN, SI .
JOURNAL OF CHEMICAL PHYSICS, 1950, 18 (02) :232-233