1,2,3-OXATHIAZOLIDINES - A NEW HETEROCYCLIC SYSTEM

被引：196

作者：

DEYRUP, JA

MOYER, CL

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 01期

关键词：

D O I：

10.1021/jo00838a038

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of β-amino alcohols with thionyl chloride in the presence of base leads to 2-oxo-1,2,3-oxathiazolidines (a previously unreported heterocyclic system) in good to excellent yields. Evidence is presented for the general structure of these compounds. The existence of the asymmetry at sulfur in these compounds is discussed and the anisotropic nature of the S-O bond is used to assign stereochemistry. © 1969, American Chemical Society. All rights reserved.

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页码：175 / &

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