2ND DIMENSION IN METAL VAPOR CHEMISTRY - NEW GENERAL-SYNTHESIS FOR METAL ALKYLS

被引：41

作者：

JUHLKE, TJ ^{[1
]}

BRAUN, RW ^{[1
]}

BIERSCHENK, TR ^{[1
]}

LAGOW, RJ ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 12期

关键词：

D O I：

10.1021/ja00506a016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new synthesis has been developed for preparation of M(R)n metal alkyls and other similar compounds. The reactive free radicals CH3., CF3., and SiF3. have been cocondensed with metals on a cold finger at -196 °C and oxidize the metals to the compounds Hg(CF3)2, Te(CF3)2, Te2(CF3)2, Bi(CF3)3, Hg(CH3)2, Cd(CH3)2, Bi(CF3)3, Sn(CH3)4), Ge(CH3)4, Hg(SiF3)2. © 1979, American Chemical Society. All rights reserved.

引用

页码：3229 / 3231

页数：3

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