KINETICS OF THE CU-2+/CU+ ELECTRODE-REACTION AT GOLD IN CONCENTRATED AQUEOUS CA(CLO4)2 SOLUTIONS

被引：6

作者：

STEPNIKSWIATEK, B

MALYSZKO, J

机构：

[1] JAN KOCHANOWSKI UNIV HUMANITIES & SCI, INST CHEM, PL-25020 KIELCE, POLAND

[2] PEDAGOG & AGR UNIV SIEDLCE, DEPT CHEM, PL-08110 SIEDLCE, POLAND

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 292卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(90)87334-G

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The kinetics of the electrochemical reaction in the Cu(II)/Cu(I) system at gold have been investigated in highly concentrated aqueous Ca(ClO4)2 solutions by means of the rotating disc electrode technique. On the basis of the kinetic data, the orders of the cathodic and anodic reactions with respect to water were determined, and a mechanism of the reaction is postulated. The rate constants obtained are also discussed in terms of Marcus's theory. © 1990.

引用

页码：175 / 185

页数：11

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