EQUILIBRIUM STRUCTURE OF BERYLLIUM DIFLUORIDE FROM LEAST-SQUARES ANALYSIS OF GAS-PHASE ELECTRON-DIFFRACTION DATA

被引：13

作者：

VOGT, N ^{[1
]}

GIRICHEV, GV ^{[1
]}

VOGT, J ^{[1
]}

GIRICHEV, AG ^{[1
]}

机构：

[1] STATE ACAD CHEM TECHNOL,DEPT PHYS,IVANOVO 153460,RUSSIA

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1995年 / 352卷

关键词：

D O I：

10.1016/0022-2860(94)08503-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The molecular structure of beryllium difluoride has been studied by means of gas-phase electron diffraction. The thermal average (r(g)) bond length Be-F at 758 degrees C is 1.386(3) Angstrom. The equilibrium structure is linear with the bond length 1.374(4) Angstrom. Force constants and vibrational frequencies have been obtained from gas-phase electron diffraction data alone.

引用

页码：175 / 179

页数：5

共 28 条

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