THERMAL-DECOMPOSITION OF ALLYLIC SULFINIC ACIDS - A STUDY OF A RETRO-ENE TRANSITION-STATE

被引：6
|
作者：
HISCOCK, SD
ISAACS, NS
KING, MD
YOUNG, DJ
机构：
[1] UNIV READING, DEPT CHEM, READING RG6 2AD, BERKS, ENGLAND
[2] GRIFFITH UNIV, FAC SCI & TECHNOL, BRISBANE, QLD 4111, AUSTRALIA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期
关键词：
D O I：
10.1039/c39940001381
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.
引用
收藏
页码：1381 / 1382
页数：2
相关论文
共 39 条
  • [21] STUDY OF THE THERMAL-DECOMPOSITION OF CELLULOSE-HYPHAN AND ITS COMPLEXES WITH SOME TRANSITION AND INDIUM METAL-IONS
    KENAWY, IMM
    HAFEZ, MAH
    ELSAID, KS
    JOURNAL OF THERMAL ANALYSIS, 1994, 42 (06): : 1143 - 1154
  • [22] STUDY OF DECOMPOSITION OF HYDROGEN-PEROXIDE ON SILVER IN A CATALYTIC FIXED-BED REACTOR - RESULTS OBTAINED IN TRANSITION-STATE
    VANTELON, JP
    BERNARD, ML
    JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1974, 71 (11-1) : 1423 - 1428
  • [23] NON-ISOTHERMAL DIFFERENTIAL THERMAL-ANALYSIS IN THE STUDY OF THE INITIAL-STAGE OF THE THERMAL-DECOMPOSITION OF POLYNITROAROMATIC COMPOUNDS IN THE CONDENSED STATE
    ZEMAN, S
    THERMOCHIMICA ACTA, 1980, 39 (02) : 117 - 124
  • [24] Highly Rotationally Excited N2 Reveals Transition-State Character in the Thermal Decomposition of N2O on Pd(110)
    Quan, Jiamei
    Yin, Rongrong
    Zhao, Zibo
    Yang, Ximei
    Kandratsenka, Alexander
    Auerbach, Daniel J.
    Wodtke, Alec M.
    Guo, Hua
    Park, G. Barratt
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (22) : 12044 - 12050
  • [25] EVIDENCE FOR A PLANAR TRANSITION-STATE IN PERICYCLIC REACTIONS INVOLVING ACETYLENES - HAMMETT STUDY OF THERMAL CLEAVAGE OF BETA-HYDROXYACETYLENES
    VIOLA, A
    PROVERB, RJ
    YATES, BL
    LARRAHON.J
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (11) : 3609 - 3613
  • [26] THERMAL-DECOMPOSITION STUDIES .8. DYNAMIC-THERMOGRAVIMETRIC STUDY OF MECHANISM OF DEAMINATION OF SOME TRANSITION-METAL COMPLEXES
    NAIR, CGR
    MADHUSUDANAN, PM
    THERMOCHIMICA ACTA, 1976, 14 (03) : 373 - 382
  • [27] A STUDY ON SOLID-STATE THERMAL-DECOMPOSITION CHARACTERISTICS OF SOME METALLO-ORGANIC COMPOUNDS .2. THERMAL DEHYDRATION AND DECOMPOSITION CHARACTERISTICS OF SOME HYDRATED METAL MALONATES
    GHOSH, S
    RAY, SK
    RAY, PK
    BANERJEE, TK
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1984, 61 (10) : 850 - 855
  • [28] A STUDY ON SOLID-STATE THERMAL-DECOMPOSITION CHARACTERISTICS OF SOME METALLO-ORGANIC COMPOUNDS .1. DEHYDRATION AND DECARBOXYLATION OF HYDRATED CALCIUM SALTS OF PYRIDINE MONOCARBOXYLIC ACIDS
    GHOSH, S
    RAY, SK
    RAY, PK
    BANDYOPADHYAY, TK
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1982, 59 (09) : 1034 - 1037
  • [29] THERMAL-DECOMPOSITION OF [RNNH4-N]2TECL6 IN THE SOLID-STATE - PHASE-TRANSITION IN DIETHYLAMMONIUM HEXACHLOROTELLURATE
    GRIGORYEVA, TF
    SAMSONOVA, TI
    BAIDINA, IA
    IVANOV, EY
    IZVESTIYA SIBIRSKOGO OTDELENIYA AKADEMII NAUK SSSR SERIYA KHIMICHESKIKH NAUK, 1985, (05): : 29 - 34
  • [30] Thermal Study in Solid State of Zn(II)-Diclofenac Complex: Behavior Kinetic of the Dehydration, Transition Phase and Thermal Decomposition
    Kobelnik, Marcelo
    Quarcioni, Valdecir Angelo
    Ribeiro, Clovis Augusto
    Vieira Capela, Jorge Manuel
    Dias, Diogenes dos Santos
    Crespi, Marisa Spirandeli
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2010, 57 (3A) : 384 - 390
1234