FOURIER-TRANSFORM INFRARED STUDY OF AMORPHOUS N2O4 SOLID - DESTABILIZATION WITH INERT IMPURITIES

被引：31

作者：

GIVAN, A ^{[1
]}

LOEWENSCHUSS, A ^{[1
]}

机构：

[1] HEBREW UNIV JERUSALEM,DEPT INORGAN & ANALYT CHEM,IL-91904 JERUSALEM,ISRAEL

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 11期

关键词：

D O I：

10.1063/1.460192

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Amorphous N2O4 solid was formed on predeposited oxygen or krypton layers. Evaporation of the underlying layer and redeposition of the inert impurities resulted in decomposition of the ionic nitrosonium nitrate clusters within the solid nitrogen tetroxide. Infrared features indicate NO+NO3- decomposition to occur via molecular NONO3, with NO2 monomers as products. Evaporation of the inert impurities and recooling restored the amorphous N2O4 from which NO+NO3- was formed again.

引用

页码：7562 / 7563

页数：2

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