KINETICS OF THE THERMAL-DECOMPOSITION OF DIMETHYLCADMIUM

被引：0
|
作者：
SMIRNOV, VN
VOTINTSEV, VN
ZASLONKO, IS
MOISEEV, AN
机构：
来源：
KINETICS AND CATALYSIS | 1990年 / 31卷 / 05期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Rate constants of the thermal decomposition of dimethylcadmium are measured in shock waves at 1000-1250 K and [M] = 2.5 x 10(-6)-2.5 x 10(-5) mole/cm. The limiting step in the process is the rupture of the first Cd-C bond. From a comparison with calculations according to the RRKM theory, an expression is obtained for the rate constant of the homogeneous, thermal decomposition of Cd(CH3)2 in the limit of low and high pressures.
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页码：908 / 912
页数：5
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