MECHANISM OF CORROSION OF IRON BY HYDROCHLORIC-ACID AND ITS INHIBITION BY IODIDE AND QUINOLINE

被引：8
|
作者：
RAJAGOPALAN, KS
VENKATACHARI, G
机构：
来源：
CORROSION | 1980年 / 36卷 / 06期
关键词：
D O I：
10.5006/0010-9312-36.6.320
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The mechanism can be explained in terms of: (1) rate determining step (FeClOH)** minus //a//d//s yields FeClOH plus e for the anodic reaction, (2) reduction of H** plus ion adsorbed on the surface to 0. 5 by the addition of chloride ions, and (3) rate determining discharge of H** plus ions for the cathodic reaction. Iodide and quinoline both inhibit corrosion by coverage of the surface and do not participate in the mechanism of dissolution.
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页码：320 / 321
页数：2
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