ZINC SATURATION IN YBA2CU3O7-DELTA

被引:1
作者
DEBOECK, C
LANCKBEEN, A
VANMOER, A
DUVIGNEAUD, PH
机构
[1] Université Libre, Bruxelles - Service de Chimie Industrielle et Analytique - C.P. 165 - 50, B1050 Bruxelles, av. F.D. Roosevelt
来源
PHYSICA C | 1994年 / 235卷
关键词
D O I
10.1016/0921-4534(94)91382-X
中图分类号
O59 [应用物理学];
学科分类号
摘要
Saturation in YBa2(Cu1-xZnx)(3)O-7-delta has been studied in relation to phase composition. Nominal compositions up to x = 0.3 have been synthesized by an optimized 3 steps solid state route. Values as high as x = 0.12 were observed at nominal zinc content where secondary phases appear (x greater than or equal to 0. 1). Mixtures of pure YB2Cu3O7 delta with ZnO were also sintered. In this case, x is never higher than 0.07. Rietveld refinement applied to X-ray diffraction datas shows that the orthorhombic character of the YBa2Cu3O7-delta lattice is maintained in the range 0 less than or equal to x less than or equal to O.12. Correlations between zinc saturation and Y2O3-BaCO3-CuO phase diagram are established.
引用
收藏
页码:317 / 318
页数:2
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