APPLICATION OF A MEMBRANE REACTOR SYSTEM TO THERMAL-DECOMPOSITION OF CO2

被引:57
作者
ITOH, N [1 ]
SANCHEZ, MA [1 ]
XU, WC [1 ]
HARAYA, K [1 ]
HONGO, M [1 ]
机构
[1] UNIV NIHON,DEPT IND CHEM,NARASHINO 275,JAPAN
关键词
CERAMIC MEMBRANES; GAS SEPARATIONS; MEMBRANE REACTORS; CHEMICAL EQUILIBRIUM; CARBON DIOXIDE DECOMPOSITION;
D O I
10.1016/0376-7388(93)85073-6
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
An yttria stabilized zirconia (YSZ) membrane reactor system was applied to enhance the direct thermal decomposition of CO2 at high temperature. The decomposition rate of CO2 and the permeation rate of oxygen through the membrane were measured and their equations were established. The reaction itself and the reactions involved in the separation process were analyzed by computer simulation. It was found that the YSZ-membrane reactor system may improve the final conversion in CO2 decomposition. The experimental results were in good agreement with the model predictions presented in this study.
引用
收藏
页码:245 / 253
页数:9
相关论文
共 7 条
[1]   OXYGEN SEMIPERMEABILITY AND ELECTRONIC CONDUCTIVITY IN CALCIA-STABILIZED ZIRCONIA [J].
CALES, B ;
BAUMARD, JF .
JOURNAL OF MATERIALS SCIENCE, 1982, 17 (11) :3243-3248
[2]  
HEYNE L, 1979, P BRIT CERAMIC SOC, V19, P229
[3]   A MEMBRANE REACTOR USING PALLADIUM [J].
ITOH, N .
AICHE JOURNAL, 1987, 33 (09) :1576-1578
[4]   BASIC EXPERIMENTAL-STUDY ON PALLADIUM MEMBRANE REACTORS [J].
ITOH, N ;
XU, WC ;
HARAYA, K .
JOURNAL OF MEMBRANE SCIENCE, 1992, 66 (2-3) :149-155
[5]  
ITOH N, 1991, 56TH ANN M SOC CHEM, pC206
[6]  
ITOH N, 1991, 24TH AUT M SOC CHEM, pQ103
[7]   PRODUCTION OF CARBON-MONOXIDE BY DIRECT THERMAL SPLITTING OF CARBON-DIOXIDE AT HIGH-TEMPERATURE [J].
NIGARA, Y ;
CALES, B .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (06) :1997-2002