REVERSAL OF DIASTEREOSELECTIVITY IN THE ADDITION OF C-NUCLEOPHILES TO N-TRIMETHYLSILYL IMINES VIA GRIGNARD DERIVED ORGANO COPPER-BORON TRIFLUORIDE REAGENTS

被引：18

作者：

CAINELLI, G ^{[1
]}

GIACOMINI, D ^{[1
]}

PANUNZIO, M ^{[1
]}

ZARANTONELLO, P ^{[1
]}

机构：

[1] CNR,CSFM,I-40126 BOLOGNA,ITALY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 50期

关键词：

D O I：

10.1016/0040-4039(93)88045-K

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The N-trimethylsilyl imines of O-protected alpha-hydroxy aldehydes react with RCuMgXI BF3 to give beta-amino alcohols with high anti diastereoselectivity.

引用

页码：7783 / 7786

页数：4

共 28 条

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