PHYSICAL AND CHEMICAL CHARACTERIZATION OF MICROPOROUS ZIRCONIA

被引：134

作者：

RIGNEY, MP ^{[1
]}

FUNKENBUSCH, EF ^{[1
]}

CARR, PW ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

JOURNAL OF CHROMATOGRAPHY | 1990年 / 499卷

关键词：

D O I：

10.1016/S0021-9673(00)96980-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Small (< 10 μm) microporous zirconia has been prepared and evaluated as an alkaline stable high-performance liquid chromatographic support. Zirconia is an amphoteric metal oxide which exhibits both anion- and cation-exchange properties depending on the solution pH and the nature of the buffer. The affinity of zirconia for polyoxy anions, particularly the effect of phosphate on the properties of the zirconia, is examined. Most significantly, the exceptional stability of zirconia, even under extreme conditions, is demonstrated and compared to the stability of alumina. © 1990.

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页码：291 / 304

页数：14

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