THE SOLUBILITY OF CAO-CENTER-DOT-CR2O3 IN THE CAO-CAF2 SYSTEM ASSOCIATED WITH DEPHOSPHORIZATION OF FE-CR-C MELTS

被引:5
作者
KANZAKI, Y [1 ]
TSUKIHASHI, F [1 ]
SANO, N [1 ]
机构
[1] UNIV TOKYO,FAC ENGN,BUNKYO KU,TOKYO,TOKYO 113,JAPAN
来源
TETSU TO HAGANE-JOURNAL OF THE IRON AND STEEL INSTITUTE OF JAPAN | 1994年 / 80卷 / 01期
关键词
STEELMAKING; THERMODYNAMICS; SOLUBILITY; CHROMIUM STEEL; CALCIUM CHROMITE; CAO-CAF2; SYSTEM; DEPHOSPHORIZATION; FE-CR-C ALLOY;
D O I
10.2355/tetsutohagane1955.80.1_13
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The solubility of chromium oxide in the CaO-CaF2 system has been determined at 1773K by equilibrating the flux with a CaO.Cr2O3 pellet at the oxygen partial pressure of 2.28 x 10(-7) Pa. The solubility of Cr2O3 varies from 0.80 to 1.28 mass% in the flux with increasing the CaO content from 15.6 to 20.6 mass%. In case of the dephosphorization of Fe-Cr-C melts with CaO bearing fluxes, the prevailing oxygen partial pressure of the system is controlled by the reaction between CaO and Cr2O3 forming CaO.Cr2O3. The phosphorus distribution ratio between Fe-Cr-C-satd. alloys and CaO-SiO2-CaF2 fluxes saturated with CaO.Cr2O3, CaO and 3CaO.SiO2 has been measured at 1573K. The phosphorus and chromium distribution ratios decrease with increasing chromium content of the metal from 1 to 13 mass%.
引用
收藏
页码:13 / 17
页数:5
相关论文
共 8 条
  • [1] FROHBERG MG, 1968, ARCH EISENHUTTENWES, V39, P585
  • [2] GRIFFING NR, 1962, T METALL SOC AIME, V224, P148
  • [3] Mohanty A. K., 1975, Metallurgical Transactions B (Process Metallurgy), V6B, P159, DOI 10.1007/BF02825690
  • [4] OHTANI M, 1956, SCI REP RES I TOHO A, V8, P337
  • [5] THERMODYNAMICS OF PHOSPHORUS IN CAO-CAF2-SIO2 AND CAO-CAF2-CACL2 MELTS SATURATED WITH CAO
    SANO, N
    TSUKIHASHI, F
    TAGAYA, A
    [J]. ISIJ INTERNATIONAL, 1991, 31 (11) : 1345 - 1347
  • [6] ACTIVITY OF PHOSPHORUS IN MOLTEN IRON AND ITS CONTROL BY NICKEL, MAGANESE AND CHROMIUM
    SCHENCK, H
    STEINMET.E
    GITIZAD, H
    [J]. ARCHIV FUR DAS EISENHUTTENWESEN, 1969, 40 (08): : 597 - &
  • [7] Turkdogan ET., 1980, PHYS CHEM HIGH TEMPE, P7
  • [8] Wagner C., 1975, Metallurgical Transactions B (Process Metallurgy), V6B, P405, DOI 10.1007/BF02913825