共 50 条
SYNTHESES AND STRUCTURES OF FUNCTIONAL SUBSTITUTED FERROCENES
被引:10
|作者:
GRUNHAGEN, A
[1
]
PIEPER, U
[1
]
KOTTKE, T
[1
]
ROESKY, HW
[1
]
机构:
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY
来源:
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
|
1994年
/
620卷
/
04期
关键词:
N;
O-BIS(TRIMETHYLSILYL)FERROCENYLIMIDATE;
E;
Z-(FERROCENYL-TRIMETHYLSILOXYMETHYLIDEN)TRIMETHYLSILYLPHOSPHANE;
D O I:
10.1002/zaac.19946200422
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Substituted ferrocenes have been prepared using carbonic acid chloride of ferrocene. New pathways have been found reacting the acid chloride with sodium hexamethyldisilazane and tris(trimethylsilyl)phosphane, respectively. The compounds FecC(OSiMe3)N(SiMe3) (Fec = C5H5FeC5H4) 1 and FecC(OSiMe3)P(SiMe3) 2 have been obtained and characterized by X-ray single crystal structure analysis. Experiments for the preparation of FecCP 3 are reported.
引用
收藏
页码:716 / 722
页数:7
相关论文