STRUCTURAL AND KINETIC FEATURES OF CRYSTAL-GROWTH INHIBITION - ADIPIC ACID GROWING IN THE PRESENCE OF N-ALKANOIC ACIDS

被引：47

作者：

DAVEY, RJ ^{[1
]}

BLACK, SN ^{[1
]}

LOGAN, D ^{[1
]}

MAGINN, SJ ^{[1
]}

FAIRBROTHER, JE ^{[1
]}

GRANT, DJW ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT PHARM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1992年 / 88卷 / 23期

关键词：

D O I：

10.1039/ft9928803461

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Optical microscopy, crystal growth kinetics and induction time measurements have been utilised to characterise the influence of n-alkanoic acids on the crystallisation of adipic acid from aqueous solution. The kinetic and morphological data are consistent with a structural model in which the added n-alkanoic acids occupy lattice sites at the crystal surfaces. This is confirmed by the observed incorporations of these molecules at detectable levels in the harvested crystals.

引用

页码：3461 / 3466

页数：6

共 28 条

[1] A LINK BETWEEN MACROSCOPIC PHENOMENA AND MOLECULAR CHIRALITY - CRYSTALS AS PROBES FOR THE DIRECT ASSIGNMENT OF ABSOLUTE-CONFIGURATION OF CHIRAL MOLECULES [J].