ANHYDROUS DEPROTECTION OF DIMETHYL ACETALS WITH ACETYL CHLORIDE/ZNCL2

被引：11

作者：

CHANG, C ^{[1
]}

CHU, KC ^{[1
]}

YUE, S ^{[1
]}

机构：

[1] DEV CTR BIOTECHNOL,TAIPEI,TAIWAN

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 08期

关键词：

D O I：

10.1080/00397919208021108

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dimethyl acetals are converted to the corresponding aldehyde in THF with acetyl chloride/zinc chloride in the presence of dimethyl sulfide.

引用

页码：1217 / 1220

页数：4

共 8 条

[1] ACETOLYSIS OF CYCLIC ACETALS - REGIOSELECTIVE ACYLATIVE CLEAVAGE OF CYCLIC FORMALS [J].

BAILEY, WF ;

RIVERA, AD .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (25) :4958-4964

[2] ACYCLIC NUCLEOSIDE ANALOGS - SYNTHESIS OF OPEN-RING RIBOSIDE OR DEOXYRIBOSIDE ANALOGS LACKING C(3') OR THE C(3')-C(4') BOND [J].

BRYANT, JD ;

KEYSER, GE ;

BARRIO, JR .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (21) :3733-3734

[3]

ELLISON RA, 1975, TETRAHEDRON LETT, P499

[4] CLEAVAGE OF METHOXYMETHYL ETHERS WITH BCL3 - A CONVENIENT, VERSATILE PREPARATION OF CHLOROMETHYL ETHER DERIVATIVES [J].

GOFF, DA ;

HARRIS, RN ;

BOTTARO, JC ;

BEDFORD, CD .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (24) :4711-4714

[5] RING CLEAVAGE OF THP AND THF ETHERS USING DIMETHYLBORON BROMIDE [J].

GUINDON, Y ;

BERNSTEIN, MA ;

ANDERSON, PC .

TETRAHEDRON LETTERS, 1987, 28 (20) :2225-2228

[6]

NICANTYEV EE, 1982, SYNTHESIS-STUTTGART, P132

[7]

POULAIN G, 1964, B SOC CHIM FR, P488

[8] EPOXYETHERS .17. SYNTHESIS FROM AN ALPHA-CHLORO-BETA-HYDROXYETHER [J].

STEVENS, CL ;

MCLEAN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (01) :119-122

← 1 →