MOLECULAR RECOGNITION BY A CATIONIC CAGE-TYPE HOST BEARING CHIRAL BINDING-SITES

被引：21
|
作者：
MURAKAMI, Y
OHNO, T
HAYASHIDA, O
HISAEDA, Y
机构：
来源：
CHEMISTRY LETTERS | 1991年 / 09期
关键词：
D O I：
10.1246/cl.1991.1595
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The guest-binding behavior of a novel cage-type host bearing chiral binding sites was examined in aqueous media. The binding constants for inclusion of non-ionic and anionic dyes were in the order of 10(5)-10(6) mol-1 dm3, and the circular dichroism was induced on an incorporated achiral guest through its stereochemical interaction with the chiral host cavity.
引用
收藏
页码：1595 / 1598
页数：4
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