MOLECULAR RECOGNITION BY A CATIONIC CAGE-TYPE HOST BEARING CHIRAL BINDING-SITES

被引：21

作者：

MURAKAMI, Y

OHNO, T

HAYASHIDA, O

HISAEDA, Y

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 09期

关键词：

D O I：

10.1246/cl.1991.1595

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The guest-binding behavior of a novel cage-type host bearing chiral binding sites was examined in aqueous media. The binding constants for inclusion of non-ionic and anionic dyes were in the order of 10(5)-10(6) mol-1 dm3, and the circular dichroism was induced on an incorporated achiral guest through its stereochemical interaction with the chiral host cavity.

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页码：1595 / 1598

页数：4

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