X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF ELECTRODE SURFACES USING A NEW CONTROLLED TRANSFER TECHNIQUE .1. DESCRIPTION OF APPARATUS AND PRELIMINARY STUDIES

被引：20

作者：

ANSELL, RO ^{[1
]}

DICKINSON, T ^{[1
]}

POVEY, AF ^{[1
]}

SHERWOOD, PMA ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE, SCH CHEM, NEWCASTLE UPON TYNE NE1 7RU, TYNE & WEAR, ENGLAND

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 98卷 / 01期

关键词：

D O I：

10.1016/S0022-0728(79)80285-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The design and use of an apparatus suitable for the controlled transfer of an electrode from an electrolyte solution to a high vacuum spectrometer chamber is described. Preliminary experiments with a nickel electrode illustrate the ability to transfer a non-noble metal without oxidation of the surface. Polarisation of a stainless steel electrode at progressively more cathodic potentials shows the gradual reduction of the oxide film present on the 'as received' material. © 1979 Elsevier Sequoia S.A.

引用

页码：69 / 77

页数：9

共 12 条

[1] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDY OF FILMS ON COLORED STAINLESS-STEEL AND COLORED NILOMAG ALLOY-771 [J].

ANSELL, RO ;

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CORROSION SCIENCE, 1978, 18 (03) :245-256

[2] QUANTITATIVE USE OF ANGULAR VARIATION TECHNIQUE IN STUDIES OF TIN BY X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

ANSELL, RO ;

DICKINSON, T ;

POVEY, AF ;

SHERWOOD, PMA .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1977, 11 (03) :301-313

[3] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF TIN ELECTRODES AFTER POLARIZATION IN SODIUM-HYDROXIDE SOLUTION [J].

ANSELL, RO ;

DICKINSON, T ;

POVEY, AF ;

SHERWOOD, PMA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1977, 124 (09) :1360-1364

[4] USE OF X-RAY PHOTOELECTRON-SPECTROSCOPY IN ANALYSES OF PASSIVE LAYERS ON STAINLESS-STEEL [J].

CASTLE, JE ;

CLAYTON, CR .

CORROSION SCIENCE, 1977, 17 (01) :7-26

[5] DISSOLUTION AND PASSIVATION OF NICKEL - X-RAY PHOTOELECTRON SPECTROSCOPIC STUDY [J].

DICKINSON, T ;

POVEY, AF ;

SHERWOOD, PMA .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1977, 73 :327-343

[6] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF OXIDE-FILMS ON PLATINUM AND GOLD ELECTRODES [J].

DICKINSON, T ;

POVEY, AF ;

SHERWOOD, PMA .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1975, 71 (02) :298-311

[7]

DICKINSON T, 1976, J CHEM SOC FARAD T 1, V72, P686, DOI 10.1039/f19767200686

[8]

HAMMOND JS, 1977, J ELECTROANAL CHEM, V78, P55

[9]

HUBBARD AT, 1974, P S ELECTROCATALYSIS, P258

[10]

OGRADY WE, 1976, 27TH M INT SOC EL ZU

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