THERMAL-DECOMPOSITION OF ALPHA-DIAZO-ALPHA-(TRIALKYLSILYL)ALKANONES - INTRAMOLECULAR C/H INSERTION OF SILOXYALKYLIDENECARBENE INTERMEDIATES

被引:28
作者
BRUCKMANN, R [1 ]
MAAS, G [1 ]
机构
[1] UNIV KAISERSLAUTERN,FACHBEREICH CHEM,POSTFACH 3049,D-6700 KAISERSLAUTERN,FED REP GER
来源
CHEMISCHE BERICHTE-RECUEIL | 1987年 / 120卷 / 04期
关键词
D O I
10.1002/cber.19871200428
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:635 / 641
页数:7
相关论文
共 55 条
[1]   TOTAL SYNTHESIS OF (+/-)-CLOVENE - ON THE STEREOELECTRONIC REQUIREMENTS OF THE ALPHA-ALKYNONE CYCLIZATION [J].
ACKROYD, J ;
KARPF, M ;
DREIDING, AS .
HELVETICA CHIMICA ACTA, 1984, 67 (07) :1963-1971
[2]   STUDY ON DIAZO-COMPOUNDS AND AZIDES .63. SILYLATION OF ALPHA-DIAZOPHOSPHONE AND DIAZOCARBON ACID-ESTERS WITH SILYL TRIFLATES [J].
ALLSPACH, T ;
GUMBEL, H ;
REGITZ, M .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 290 (01) :33-39
[3]   PHOTO-CHEMICAL DECOMPOSITION OF TRIMETHYLSILYL DIAZOACETATES IN ALCOHOLS [J].
ANDO, W ;
SEKIGUCHI, A ;
HAGIWARA, T ;
MIGITA, T ;
CHOWDHRY, V ;
WESTHEIMER, FH ;
KAMMULA, SL ;
GREEN, M ;
JONES, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (21) :6393-6398
[4]   1,2-SILAOXETANE - ISOLATION AND CHARACTERIZATION IN THE REACTION OF SILAETHYLENE WITH KETONE [J].
ANDO, W ;
SEKIGUCHI, A ;
SATO, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (24) :6830-6831
[5]   GAS-PHASE PYROLYSIS OF PHENYLTRIMETHYLSILYLDIAZOMETHANE - INTRAMOLECULAR CHEMISTRY OF PHENYLTRIMETHYLSILYLCARBENE [J].
ANDO, W ;
SEKIGUCHI, A ;
ROTHSCHILD, AJ ;
GALLUCCI, RR ;
JONES, M ;
BARTON, TJ ;
KILGOUR, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (21) :6995-6999
[6]   A HIGHLY EFFICIENT REACTION OF THIOBENZOPHENONE FOR 1-DIAZOALKENE [J].
ANDO, W ;
FURUHATA, T ;
TAKATA, T .
TETRAHEDRON LETTERS, 1985, 26 (37) :4499-4500
[7]   NEW METHODS AND REAGENTS IN ORGANIC-SYNTHESIS .8. TRIMETHYLSILYLDIAZOMETHANE, A NEW, STABLE, AND SAFE REAGENT FOR THE CLASSICAL ARNDT-EISTERT SYNTHESIS [J].
AOYAMA, T ;
SHIOIRI, T .
TETRAHEDRON LETTERS, 1980, 21 (46) :4461-4462
[8]   Syntheses with diazo methane, V: On the reaction of acid chlorides with diazo methane. [J].
Arndt, F ;
Amende, J .
BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1928, 61 :1122-1124
[9]  
Arndt F., 1943, ORG SYNTH, VII, P165