STRUCTURE AND PHOTOPHYSICS OF DEAZABIPYRIDYLS - EXCITED INTERNALLY HYDROGEN-BONDED SYSTEMS WITH ONE PROTON-TRANSFER REACTION SITE

被引：49

作者：

KACZMAREK, L ^{[1
]}

BALICKI, R ^{[1
]}

LIPKOWSKI, J ^{[1
]}

BOROWICZ, P ^{[1
]}

GRABOWSKA, A ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST PHYS CHEM,PL-01224 WARSAW,POLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1994年 / 07期

关键词：

D O I：

10.1039/p29940001603

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two deazabipyridyls, 2-(2-hydroxyphenyl)pyridin-3-ol 1 and 2-(2-pyridyl)phenol 2, are the objects of X-ray and spectroscopic studies. Their syntheses, crystal structures and photophysics in comparison with [2,2'-bipyridyl]-3,3'-diol and [2,2'-bipyridyl]-3-ol 3 are described. The influence of the molecular structure on the efficiency of the proton-transfer reaction in the S1 state is discussed. The experimental data are compared with semiempirical quantum chemical calculations.

引用

页码：1603 / 1610

页数：8

共 31 条

[1] TAUTOMERIZATION IN FLUORESCENT STATES OF BIPYRIDYL-DIOLS - A DIRECT CONFIRMATION OF THE INTRAMOLECULAR DOUBLE PROTON-TRANSFER BY ELECTROOPTICAL EMISSION MEASUREMENTS
BOROWICZ, P
GRABOWSKA, A
WORTMANN, R
LIPTAY, W
[J]. JOURNAL OF LUMINESCENCE, 1992, 52 (5-6) : 265 - 273
[2] A NEW FLUORESCENCE STANDARD
BULSKA, H
[J]. JOURNAL OF LUMINESCENCE, 1988, 39 (06) : 293 - 299
[3] INTRAMOLECULAR COOPERATIVE DOUBLE PROTON-TRANSFER IN [2,2'-BIPYRIDYL]-3,3'-DIOL
BULSKA, H
[J]. CHEMICAL PHYSICS LETTERS, 1983, 98 (04) : 398 - 402
[4] SINGLE AND DOUBLE PROTON-TRANSFER IN EXCITED HYDROXY DERIVATIVES OF BIPYRIDYL
BULSKA, H
GRABOWSKA, A
GRABOWSKI, ZR
[J]. JOURNAL OF LUMINESCENCE, 1986, 35 (04) : 189 - 197
[5] Coulson DR, 1971, INORG SYN, V13, P121, DOI DOI 10.1002/9780470132449.CH23
[6] ABSORPTION, EMISSION AND LIFETIMES OF [2,2'-BIPYRIDYL]-3,3'-DIOL IN SOL-GEL GLASSES AND IN POLYMETHYLMETHACRYLATE
EYAL, M
REISFELD, R
CHERNYAK, V
KACZMAREK, L
GRABOWSKA, A
[J]. CHEMICAL PHYSICS LETTERS, 1991, 176 (06) : 531 - 535
[7] THE SYNTHESIS OF SOME INTERMEDIATES FOR USE IN THE PREPARATION OF ANALOGS OF SALICYLALDEHYDE ETHYLENEDIIMINE COBALT (SALCOMINE)
GEISSMAN, TA
SCHLATTER, MJ
WEBB, ID
ROBERTS, JD
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1946, 11 (06) : 741 - 750
[8] GRABOWSKA A, 1990, Patent No. 257033
[9] Grabowska A, 1992, POL J CHEM, V66, P715
[10] EXCITED-STATE BEHAVIOR OF 1,2-DI(2-PYRIDYL)-1,2-ETHENEDIOL (ALPHA-PYRIDOIN) AND ITS BORIC-ACID COMPLEXES
GUDIPATI, MS
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (33) : 8602 - 8607

← 1 2 3 4 →