THE STRUCTURE OF ACUMINITE, A STRONTIUM ALUMINUM FLUORIDE MINERAL

被引:3
作者
ANDERSEN, EK [1 ]
PLOUGSORENSEN, G [1 ]
LEONARDSEN, E [1 ]
机构
[1] UNIV COPENHAGEN,INST MINERAL,OSTERVOLDGADE 10,DK-1350 COPENHAGEN K,DENMARK
来源
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1991年 / 194卷 / 3-4期
关键词
MINERAL; STRONTIUM ALUMINUM FLUORIDE; CRYSTAL STRUCTURE; ACUMINITE;
D O I
10.1524/zkri.1991.194.3-4.221
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
An X-ray diffraction study of single crystals of acuminite, a strontium aluminum fluoride mineral from Ivigtut, Greenland [SrAlF4(OH).H2O, a = 13.223(1) angstrom, b = 5.175(1) angstrom, c = 14.251(1) angstrom, beta = 111.61(2), C2/c, Z = 8, D(m) = 3.295 g cm-3, D(c) = 3.305 g cm-3] used 2138 diffraction intensities (CAD-4 diffractometer), and was refined to R (unweighted) = 0.069. The strontium ions are 9-coordinated to 7 fluoride ions and 2 water molecules, the aluminium ions have octahedral coordination, 4 fluoride ions and 2 hydroxyl ions. The structure of acuminite is compared with the structure of tikhoenkovite another modification of SrAlF4(OH).H2O.
引用
收藏
页码:221 / 227
页数:7
相关论文
共 6 条
[1]  
DONNAY G, 1970, AM MINERAL, V55, P1003
[2]  
PAULY H, 1987, NEUES JB MINER MONAT, V11, P502
[3]  
PUDOVKIN.ZV, 1967, DOKL AKAD NAUK SSSR+, V174, P193
[4]  
SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA
[5]  
STEWART JM, 1976, TR446 U MAR COMP SCI
[6]  
1962, INT TABLES XRAY CRYS, V3, P201