A NOVEL PROBE FOR FREE-RADICALS FEATURING EPOXIDE CLEAVAGE

被引：48

作者：

DICKINSON, JM ^{[1
]}

MURPHY, JA ^{[1
]}

PATTERSON, CW ^{[1
]}

WOOSTER, NF ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 04期

关键词：

D O I：

10.1039/p19900001179

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper describes the identification of carbon-carbon bond cleavage within a defined range of epoxides as being a reaction type which is specifically diagnostic of free radicals adjacent to the epoxide. The speed of the epoxide cleavage is greater than that of hex-5-enyl radical cyclisation, and hence the reaction is kinetically competent to act as a new and discriminating type of probe for free radicals in solution.

引用

页码：1179 / 1184

页数：6

共 19 条

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