REDUCTIVE MONO-ALPHA AND TRANS-ALPHA, ALPHA'-DIALLYLATION OF AROMATIC NITROGEN-HETEROCYCLES BY ALLYLBORANES

被引：36
作者：
BUBNOV, YN
机构：
[1] N.D.Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, B-334 Leninsky prosp., 47. Russia
来源：
PURE AND APPLIED CHEMISTRY | 1994年 / 66卷 / 02期
关键词：
D O I：
10.1351/pac199466020235
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reductive trans-alpha,alpha-diallylation of pyridines, 4,4'-dipyridyl, pyrrole and isoquinoline as well as reductive monoallylation of pyrrole, indole, quinolines, isoquinoline and phenanthridine by allylic boranes were discovered A convenient method for trans- --> cis-isomerization of trans-2,6-diallyl-DELTA3-piperideines and trans-2,5-diallylpyrrolidine was found.
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页码：235 / 244
页数：10
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