FLUXIONAL BEHAVIOR OF GROUP-4 TRIMETHYLINDENYL COMPOUNDS

被引：75

作者：

RAKITA, PE

DAVISON, A

机构：

[1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 05期

关键词：

D O I：

10.1021/ic50075a028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The indenyltrimethyl compounds of silicon, germanium, and tin have been investigated by variable-temperature proton magnetic resonance spectroscopy and shown to be fluxional molecules. For (CH3)3SnC9H7, the complete range from limiting high-to limiting low-temperature behavior was observed. The presence of tin to ring hydrogen coupling confirms the zroiramolecular nature of the rearrangement. Relative signs of the proton-proton and tin-proton coupling constants in (CH3)3SnC9H7 have been determined. © 1969, American Chemical Society. All rights reserved.

引用

页码：1164 / &

共 7 条

[1] STEREOCHEMICALLY NONRIGID ORGANOMETALLIC MOLECULES .8. FURTHER STUDIES OF SIGMA-CYCLOPENTADIENYLMETAL COMPOUNDS [J].