PREPARATION, CRYSTAL AND ELECTRONIC-STRUCTURES, AND ELECTRICAL-RESISTIVITY OF (BEDT-TTF)3CL2.5(H5O2)

被引：11

作者：

MORI, H ^{[1
]}

HIRABAYASHI, I ^{[1
]}

TANAKA, S ^{[1
]}

MARUYAMA, Y ^{[1
]}

机构：

[1] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 08期

关键词：

D O I：

10.1246/bcsj.66.2156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal and electronic structures and electrical resistivity of new chlorine complex, (BEDT-TTF)3Cl2.5(H5O2), were investigated. The two-dimensional donor sheet and the anion layer stack alternately along the b-axis. The packing pattern of donors is similar to that of (BEDT-TTF)3(ClO4)2 and the sharp metal-insulator transition was observed at 170 K. It is interesting that not only donor and anion but also the third component cation, H+, determines the 3/4-filled band structure.

引用

页码：2156 / 2159

页数：4

共 16 条

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