PREPARATION, CRYSTAL AND ELECTRONIC-STRUCTURES, AND ELECTRICAL-RESISTIVITY OF (BEDT-TTF)3CL2.5(H5O2)

被引：11
作者：
MORI, H [1 ]
HIRABAYASHI, I [1 ]
TANAKA, S [1 ]
MARUYAMA, Y [1 ]
机构：
[1] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 08期
关键词：
D O I：
10.1246/bcsj.66.2156
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal and electronic structures and electrical resistivity of new chlorine complex, (BEDT-TTF)3Cl2.5(H5O2), were investigated. The two-dimensional donor sheet and the anion layer stack alternately along the b-axis. The packing pattern of donors is similar to that of (BEDT-TTF)3(ClO4)2 and the sharp metal-insulator transition was observed at 170 K. It is interesting that not only donor and anion but also the third component cation, H+, determines the 3/4-filled band structure.
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页码：2156 / 2159
页数：4
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