SPECTROSCOPIC STUDIES OF THE RADICAL-ANION OF C-60 - DETECTION OF THE FLUORESCENCE AND REINVESTIGATION OF THE ESR-SPECTRUM

被引：99

作者：

KATO, T ^{[1
]}

KODAMA, T ^{[1
]}

SHIDA, T ^{[1
]}

机构：

[1] KYOTO UNIV,FAC SCI,DEPT CHEM,KYOTO 60601,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 205卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(93)87142-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An emission band with a mirror image pattern to the near-IR absorption band is detected for C60--produced electrolytically in a solution at room temperatures. The emission band reinforces our previous assignment of the absorption band. The lineshape of the ESR spectrum was reinvestigated to conclude that the isotropic feature at temperatures above 50 K is mainly due to the averaging of the Jahn-Teller distorted structures by pseudo-rotation. The significance of the residual orbital angular momentum is discussed.

引用

页码：405 / 409

页数：5

共 50 条

[41] ESR AND ENDOR STUDIES OF A RADICAL-ANION WITH FORMALLY NONCONJUGATED KETO GROUPS - CIS-10,11-DIMETHYLDIPHENSUCCINDAN-9,12-DIONE
FURDERER, P
GERSON, F
HEINZER, J
MAZUR, S
OHYANISHIGUCHI, H
SCHROEDER, AH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (09) : 2275 - 2281
[42] ULTRAFAST SPECTROSCOPIC STUDIES OF PHOTOINDUCED ELECTRON-TRANSFER FROM SEMICONDUCTING POLYMERS TO C-60
KRAABEL, B
MCBRANCH, D
SARICIFTCI, NS
MOSES, D
HEEGER, AJ
PHYSICAL REVIEW B, 1994, 50 (24): : 18543 - 18552
[43] ABINITIO MO STUDY OF THE C-60 ANION RADICAL - THE JAHN-TELLER DISTORTION AND ELECTRONIC-STRUCTURE
KOGA, N
MOROKUMA, K
CHEMICAL PHYSICS LETTERS, 1992, 196 (1-2) : 191 - 196
[44] EXTINCTION COEFFICIENTS OF C-60 TRIPLET AND ANION RADICAL, AND ONE-ELECTRON REDUCTION OF THE TRIPLET BY AROMATIC DONORS
BICZOK, L
LINSCHITZ, H
WALTER, RI
CHEMICAL PHYSICS LETTERS, 1992, 195 (04) : 339 - 346
[45] The universality of the electron spin relaxation in C-60 mono radical anion salts: EPR studies of the model system [P(C6H5)(4)](2)C(60)X
Gotschy, B
Volkel, G
APPLIED MAGNETIC RESONANCE, 1996, 11 (02) : 229 - 238
[46] The dispersed laser-induced fluorescence spectrum of gas-phase C-60 at 308 nm
Firth, S
Coheur, PF
Mitzner, R
Carleer, M
Campbell, EEB
Colin, R
Kroto, HW
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1997, 30 (11) : L393 - L400
[47] THEORETICAL-STUDIES ON THE STRUCTURES OF THE INTERMEDIATE C-60(CH3)(-) AND THE PRODUCT C-60(CH3)(2) AS WELL AS SPECTROSCOPIC NATURE OF THE PRODUCT
TENG, QW
FENG, JK
SUN, JZ
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1995, 16 (09): : 1431 - 1435
[48] COMMENT ON NANOSECOND-GATED DETECTION OF ROOM-TEMPERATURE FLUORESCENCE OF C-60 IN SOLUTION
SONG, NW
LEE, YJ
KIM, SK
KIM, D
PHYSICAL REVIEW LETTERS, 1994, 73 (19) : 2634 - 2634
[49] NANOSECOND-GATED DETECTION OF ROOM-TEMPERATURE FLUORESCENCE OF C-60 IN SOLUTION - REPLY
ANDREONI, A
BONDANI, M
CONSOLATI, G
PHYSICAL REVIEW LETTERS, 1994, 73 (19) : 2635 - 2635
[50] NANOSECOND-GATED DETECTION OF ROOM-TEMPERATURE FLUORESCENCE OF C-60 IN SOLUTION - COMMENT
THEWALT, MLW
PHYSICAL REVIEW LETTERS, 1995, 74 (22) : 4564 - 4564

← 1 2 3 4 5 →