Synthesis and X-ray structure of a new pyrryl substituted photochromic fulgide

被引:0
|
作者
Yu, LH
Ming, YF
Fan, MG
Zhu, Y
机构
[1] Acad Sinica, Inst Photog Chem, Beijing 100101, Peoples R China
[2] Lanzhou Univ, Natl Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
关键词
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new heterocyclic fulgide: E-(alpha)-(1,2-dimethyl-4-isopropyl-5-phenyl)-3-pyrryl ethylidene (isopropylidene) succinic anhydride (1) has been synthesized. The molecular conformation and atomic labelling structure of (1) was obtained by X-ray analyses. Compound (1) shows a twisted structure between different ring systems. The short distance between C1 atom and C22 atom (3.567 Angstrom) offers a favourable structure for the photoinduced intramolecular cyclization of 1.
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页码:297 / 300
页数:4
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