BETA-PHENYLSELENO ALPHA,BETA-UNSATURATED ALDEHYDES, EFFICIENT 3 CARBON HOMOLOGATING AGENTS - 1,3-CARBONYL TRANSPOSITION

被引：3

作者：

ARRUA, EP

COMASSETO, JV

机构：

[1] Instituto de Química - Universidade de Săo Paulo, Cx.P. 20780 - CEP 01498 - Săo Paulo, S.P.

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 15-16期

关键词：

D O I：

10.1080/00397919108021067

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The easily obtained beta-phenylseleno alpha,beta-unsaturated aldehydes react with Grignard reagents and with n-butyllithium leading to the 1,2-addition products, which upon acidic hydrolysis in the presence of silica gel afford the selenium-free alpha,beta-unsaturated carbonyl compounds with 1,3-carbonyl transposition.

引用

页码：1663 / 1666

页数：4

共 12 条

[1]

COMASSETO JV, 1987, SYNTHESIS-STUTTGART, P146

[2] STEREOSELECTIVE SYNTHESIS OF VINYLIC SELENIDES [J].