BETA-PHENYLSELENO ALPHA,BETA-UNSATURATED ALDEHYDES, EFFICIENT 3 CARBON HOMOLOGATING AGENTS - 1,3-CARBONYL TRANSPOSITION

被引：3
作者：
ARRUA, EP
COMASSETO, JV
机构：
[1] Instituto de Química - Universidade de Săo Paulo, Cx.P. 20780 - CEP 01498 - Săo Paulo, S.P.
来源：
SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 15-16期
关键词：
D O I：
10.1080/00397919108021067
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The easily obtained beta-phenylseleno alpha,beta-unsaturated aldehydes react with Grignard reagents and with n-butyllithium leading to the 1,2-addition products, which upon acidic hydrolysis in the presence of silica gel afford the selenium-free alpha,beta-unsaturated carbonyl compounds with 1,3-carbonyl transposition.
引用
收藏
页码：1663 / 1666
页数：4
相关论文
共 12 条
12