A MONONUCLEAR COPPER(II) COMPLEX OF AN UNSYMMETRICAL DINUCLEATING LIGAND

被引：23

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

FENTON, DE ^{[1
]}

PAPAGEORGIOU, G ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 11期

关键词：

D O I：

10.1039/dt9950001883

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unsymmetrical and potentially dinucleating ligand 4-bromo-2-(2-hydroxyethyliminomethyl)-6-(morpholin-4-ylmethyl)phenol (H(2)L(1)) has been prepared via a Mannich reaction under non-aqueous aprotic conditions. Reaction with copper(II) yielded mono- and di-nuclear complexes; the crystal structure of the mononuclear complex [Cu(H(2)L(1))][ClO4](2) . H2O . MeOH has been determined.

引用

页码：1883 / 1886

页数：4

共 14 条

[1]

BAILEY NA, 1994, SYNLETT, P79

[2] A MIXED-VALENT, UNSYMMETRICAL (FEFEIII)-FE-II COMPLEX WITH A TERMINAL PHENOLATO LIGAND AS A MODEL FOR THE ACTIVE-SITE OF PURPLE ACID-PHOSPHATASES [J].

BERNARD, E ;

MONETA, W ;

LAUGIER, J ;

CHARDONNOBLAT, S ;

DERONZIER, A ;

TUCHAGUES, JP ;

LATOUR, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (08) :887-889

[3] UNSYMMETRIC DICOPPER(II) COMPLEXES OF DINUCLEATING LIGANDS BEARING CHEMICALLY DISTINCT COORDINATION ENVIRONMENTS [J].

CRANE, JD ;

FENTON, DE ;

LATOUR, JM ;

SMITH, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (11) :2979-2987

[4] THE EFFECT OF SULFUR-DIOXIDE ON THE MANNICH REACTIONS OF PHENOLS [J].

FAIRHURST, RA ;

HEANEY, H ;

PAPAGEORGIOU, G ;

WILKINS, RF .

TETRAHEDRON LETTERS, 1988, 29 (45) :5801-5804

[5]

Fenton D. E., 1983, ADV INORG BIOINORG, V2, P187

[6] SYNTHESIS OF AN UNSYMMETRICAL DINUCLEATING LIGAND THAT LEADS TO AN ASYMMETRIC DICOPPER(II) COMPLEX HAVING DIFFERENT DONOR SETS AT EACH COPPER [J].

KAMARAS, P ;

CAJULIS, MC ;

RAPTA, M ;

BREWER, GA ;

JAMESON, GB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (22) :10334-10335

[7] DIFFERENT ORIGINS OF METAL-BINDING SITES IN BINUCLEAR COPPER PROTEINS, TYROSINASE AND HEMOCYANIN [J].

LERCH, K ;

HUBER, M ;

SCHNEIDER, HJ ;

DREXEL, R ;

LINZEN, B .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1986, 26 (03) :213-217

[8] 4-morpholinomethyl alkyl ethers and N-substituted morpholines [J].

Mason, JP ;

Zief, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :1450-1452

[9]

PAPAGEORGIOUS G, 1990, THESIS LOUGHBOROUGH

[10]

SHELDRICK GM, 1990, SHELXTL PC VERSION 4

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