THERMAL-DEGRADATION OF POLYESTERS BY SIMULTANEOUS TG-DTA/FT-IR ANALYSIS

被引:21
|
作者
KINOSHITA, R
TERAMOTO, Y
NAKANO, T
YOSHIDA, H
机构
[1] NIPPON BIO RAD LABS,DIV ANALYT INSTRUMENT,CHUO KU,TOKYO 104,JAPAN
[2] TOKYO METROPOLITAN UNIV,DEPT IND CHEM,HACHIOJI,TOKYO 19203,JAPAN
来源
JOURNAL OF THERMAL ANALYSIS | 1992年 / 38卷 / 08期
关键词
POLYMERS; TG-DTA/FT-IR;
D O I
10.1007/BF01974683
中图分类号
O414.1 [热力学];
学科分类号
摘要
A combination system of thermogravimetric/differential thermal analysis (TG-DTA) and Fourier-transform infrared absorption spectroscopy (FT-IR) was described. This simultaneous TG-DTA/FT-IR technique gave spectroscopic and weight loss information about the thermal degradation process of engineering polyesters; poly(ethylene terephthalate)(PET) and poly(butylene terephthalate)(PBT). The evolved gases from PET were benzoic acid, carbon dioxide and carbon monoxide, while those from PBT were terephthalic acid esters and benzoic acid esters.
引用
收藏
页码:1891 / 1900
页数:10
相关论文
共 50 条
  • [31] TG/FT-IR - AN ANALYSIS OF THE CONDITIONS AFFECTING THE COMBINED TG/SPECTRAL RESPONSE
    BERBENNI, V
    MARINI, A
    BRUNI, G
    ZERLIA, T
    THERMOCHIMICA ACTA, 1995, 258 : 125 - 133
  • [32] THERMAL-DEGRADATION OF AROMATIC POLYESTERS
    MOTOV, SA
    DANILINA, LI
    PRAVEDNIKOV, AN
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1980, 22 (10): : 2330 - 2336
  • [33] Crystallization of anodic alumina membranes studied by simultaneous TG-DTA/FTIR
    Ozao, R
    Yoshida, H
    Ichimura, Y
    Inada, T
    Ochiai, M
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2001, 64 (03): : 915 - 922
  • [34] The use of the temperature signal and its derivative in a TG-DTA simultaneous unit
    Aggarwal, P
    Dollimore, D
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1997, 50 (5-6): : 719 - 726
  • [35] Evaporation of the fragrance component, cinnamyl alcohol, using simultaneous TG-DTA
    Sorokina, TV
    Dollimore, D
    Alexander, KS
    THERMOCHIMICA ACTA, 2002, 392 : 315 - 321
  • [36] A simultaneous TG-DTA study of the degradation in nitrogen of cellulose to carbon, alone and in the presence of other pharmaceutical excipients
    Lerdkanchanaporn, S
    Dollimore, D
    Alexander, KS
    THERMOCHIMICA ACTA, 1998, 324 (1-2) : 25 - 32
  • [37] Crystallization of Anodic Alumina Membranes Studied by Simultaneous TG-DTA/FTIR
    R. Ozao
    H. Yoshida
    Y. Ichimura
    T. Inada
    M. Ochiai
    Journal of Thermal Analysis and Calorimetry, 2001, 64 : 915 - 922
  • [38] Studies on the thermal degradation of acrylic polymers by simultaneous autostep TG/DTA
    Ali, AH
    Srinivasan, KSV
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1997, A34 (02): : 235 - 246
  • [39] The use of the temperature signal and its derivative in a TG-DTA simultaneous unit
    P. Aggarwal
    D. Dollimore
    Journal of thermal analysis, 1997, 50 : 719 - 726
  • [40] An investigation of the evaporation of stearic acid using a simultaneous TG-DTA unit
    Lerdkanchanaporn, S
    Dollimore, D
    THERMOCHIMICA ACTA, 1998, 324 (1-2) : 15 - 23