MIXED QUINONE MONOKETALS VIA IODOBENZENE DIACETATE OXIDATION

被引：42

作者：

FLECK, AE ^{[1
]}

HOBART, JA ^{[1
]}

MORROW, GW ^{[1
]}

机构：

[1] UNIV DAYTON,DEPT CHEM,300 COLL PK,DAYTON,OH 45469

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 01期

关键词：

D O I：

10.1080/00397919208021090

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of p-methoxyphenol, 4-methoxynaphthol and 4-acetamidophenol with iodobenzenediacetate in various alcohols as solvent afforded the corresponding mixed quinone or naphthoquinone monoketals in good yield. Oxidation of p-methoxyphenol in the presence of sorbyl alcohol led to in situ intramolecular Diels-Alder reactions proceeding by way of the corresponding mixed quinone monoketal.

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页码：179 / 187

页数：9

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