ACID-CATALYZED COMPLEXATION OF ARENES WITH CR(CO)6

被引：5

作者：

HRNCIAR, P ^{[1
]}

TOMA, S ^{[1
]}

机构：

[1] COMENIUS UNIV BRATISLAVA,DEPT ORGAN CHEM,CS-84215 BRATISLAVA,SLOVAKIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80047-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several acids were tested as potential catalysts for complexation of arenes with Cr(CO)6 in boiling decalin. Acetic acid was found to be an efficient catalyst for complexation of acyl- and acyloxybenzenes. A mixture of butanone or cyclohexanone and acetic acid, with THF and acetic acid was found to be an efficient catalytic system or complexation of other arenes. The complex (eta-2-acenaphthylene)4Cr(CO)2 was isolated during an attempt on acetic acid catalysed complexation of acenaphthylene with Cr(CO)6.

引用

页码：161 / 164

页数：4

共 7 条

[1] A KINETIC INVESTIGATION OF ARENE EXCHANGE AND SUBSTITUTION IN (NAPHTHALENE)CR(CO)3 [J].

HOWELL, JAS ;

DIXON, DT ;

KOLA, JC ;

ASHFORD, NF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 294 (01) :C1-C4

[2]

HRNCIAR P, IN PRESS COLLECT CZE

[3] THE STUDY OF CATALYST EFFECTS ON THE COMPLEXATION OF ARENES WITH CR(CO)6 - AN OVERVIEW [J].

HUDECEK, M ;

GAJDA, V ;

TOMA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 413 (1-3) :155-160

[4] AN IMPROVED METHOD FOR THE SYNTHESIS OF ETA-6-ARENETRICARBONYLCHROMIUM COMPLEXES [J].

HUDECEK, M ;

TOMA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 393 (01) :115-118

[5] A SIMPLE ROUTE TO (ETA-6-ARENE)TRICARBONYLCHROMIUM COMPLEXES AND A SYSTEMATIC STUDY OF DIFFERENT CATALYSTS FOR COMPLEXATION OF ARENES WITH CR(CO)6 [J].

HUDECEK, M ;

TOMA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 406 (1-2) :147-151

[6] PROTONATION OF METAL-CARBONYL COMPLEXES .2. PMR SPECTROSCOPIC STUDY OF PROTONATION IN ARENECHROMIUM TRICARBONYLS AND ARENECHROMIUM DICARBONYL TRIPHENYLPHOSPHINES [J].

KURSANOV, DN ;

BARANETS.NK ;

ZDANOVIC.VI ;

SETKINA, VN ;

RUBIN, ID ;

PETROVSK.PV .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 37 (02) :339-&

[7]

SNEEDEN RPA, 1975, ORGANOCHROMIUM COMPO, P197

← 1 →