COPOLYMERIZATION OF ACRYLONITRILE WITH METHYL-METHACRYLATE INITIATED BY THIOL

被引:0
|
作者
WANG, GS
XIA, P
YAN, DY
WANG, KC
机构
[1] HUZHOU TEACHERS COLL,HUZHOU,PEOPLES R CHINA
[2] SHANGHAI JIAO TONG UNIV,DEPT APPL CHEM,SHANGHAI 200030,PEOPLES R CHINA
关键词
D O I
10.1080/00222339108054408
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this work, the authors found that thiol is capable of initiating the copolymerization of methyl methacrylate (MMA) and acrylonitrile (AN) at room temperature. The copolymerization kinetics, copolymer composition and molecular weight of the copolymer were studied. The apparent activation energy of the overall copolymerization was measured to be 143kJ/mol.
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页码:257 / 263
页数:7
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