ALKANE OXIDATION BY AN IRON COMPLEX-HYDROGEN PEROXIDE SYSTEM IN ACETONITRILE - THE MODEL OF METHANEMONOOXYGENASE

被引：24
|
作者：
KHENKIN, AM
BELOVA, VS
SHILOV, AE
机构：
[1] USSR Academy of Sciences Institute of Chemical Physics, Chernogolovka
来源：
CATALYSIS LETTERS | 1990年 / 5卷 / 02期
关键词：
enzymes; hydrocarbons; hydrogen peroxide; iron complexes; Oxidation;
D O I：
10.1007/BF00763955
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The oxidation of methane and other light alkanes in the system iron complex - hydrogen peroxide has been studied. The efficiency of this system of alkane oxidation depends on water concentration. The catalytic methanol formation from methane with respect to the binuclear iron complex has been observed. The role of iron-oxocomplexes in oxidation of alkanes by methanemonooxygenase and model systems is discussed. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.
引用
收藏
页码：211 / 216
页数：6
相关论文
共 50 条
  • [31] A new insight into the oxidation of cyclododecane with hydrogen peroxide in the presence of iron-substituted polyoxotungstates
    Santos, Isabel C. M. S.
    Simoes, Mario M. Q.
    Balula, M. Salete S.
    Neves, M. Graca P. M. S.
    Cavaleiro, Jose A. S.
    Cavaleiro, Ana M. V.
    SYNLETT, 2008, (11) : 1623 - 1626
  • [32] Alkane oxidation catalysed by a self-folded multi-iron complex
    Mettry, Magi
    Moehlig, Melissa Padilla
    Gill, Adam D.
    Hooley, Richard J.
    SUPRAMOLECULAR CHEMISTRY, 2017, 29 (02) : 120 - 128
  • [33] Non-heme iron coordination complexes for alkane oxidation using hydrogen peroxide (H2O2) as powerful oxidant
    Kejriwal, Ambica
    JOURNAL OF COORDINATION CHEMISTRY, 2022, 75 (7-8) : 937 - 971
  • [34] Iron-catalyzed asymmetric sulfide oxidation with aqueous hydrogen peroxide
    Legros, J
    Bolm, C
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (44) : 5487 - 5489
  • [35] Asymmetric oxidation catalysis by a chiral Al(salalen) complex: Highly enantioselective oxidation of sulfides with aqueous hydrogen peroxide
    Yamaguchi, Tetsufumi
    Matsumoto, Kazuhiro
    Saito, Bunnai
    Katsuki, Tsutomu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (25) : 4729 - 4731
  • [36] HYDROGEN-PEROXIDE OXIDATION ON PASSIVE IRON IN ALKALINE-SOLUTIONS
    GOJKOVIC, SL
    ZECEVIC, SK
    DRAZIC, DM
    ELECTROCHIMICA ACTA, 1992, 37 (10) : 1845 - 1850
  • [37] Silica aerogel-iron oxide nanocomposites: recoverable catalysts for the oxidation of alcohols with hydrogen peroxide
    Masoudian, Shahla
    Monfared, Hassan Hosseini
    Aghaei, Alireza
    TRANSITION METAL CHEMISTRY, 2011, 36 (05) : 521 - 530
  • [38] Remarkable structure dependence of intrinsic catalytic activity for selective oxidation of hydrocarbons with hydrogen peroxide catalyzed by iron-substituted silicotungstates
    Mizuno, N
    Kiyoto, I
    Nozaki, C
    Misono, M
    JOURNAL OF CATALYSIS, 1999, 181 (02) : 171 - 174
  • [39] Alkane oxidation by the H2O2-NaVO3-H2SO4 system in acetonitrile and water
    Shul'pina, Lidia S.
    Kirillova, Marina V.
    Pombeiro, Armando J. L.
    Shul'pin, Georgiy B.
    TETRAHEDRON, 2009, 65 (12) : 2424 - 2429
  • [40] Oxidation of Pt(II) to Pt(IV) complex with hydrogen peroxide in glycols
    Lee, YA
    Yoo, KH
    Jung, OS
    INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (03) : 249 - 251
12345