KINETICS OF PARTLY DIFFUSION CONTROLLED REACTIONS .2. COMPETITION BETWEEN PHYSICAL AND CHEMICAL-KINETICS - THEORETICAL TREATMENT

We propose a quantitative method for computing the time-dependent value of the apparent rate constant of a bimolecular reaction in the liquid phase in The model proposed permits one to determine the time-dependence of the apparent rate constant of a bimolecular process in the case where a competition The results are necessary for the understanding of the deactivation of excited electronic states by various quenchers. As a matter of fact, it appears that in numerous experimental cases, such a competition is physically significant. © 1979.