FAC-TRIS(ISOTHIOCYANATO)TRIS(TRIPHENYLPHOSPHINE OXIDE)IRON(III) AT 80K

被引:13
作者
OLEJNIK, Z [1 ]
LIS, T [1 ]
ONDREJKOVICOVA, I [1 ]
机构
[1] SLOVAK UNIV TECHNOL BRATISLAVA, DEPT INORGAN CHEM, BRATISLAVA 81237, SLOVAKIA
关键词
D O I
10.1107/S0108270195006354
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The iron(III) complex [Fe(NCS)(3)(C18H15PO)(3)] crystallizes in space group R3. One complex molecule with no crystallographically imposed symmetry and one-third of another molecule arranged about a threefold axis are contained in the asymmetric unit. Both molecules have almost the same geometry for the octahedral FeO3N3 chromophores, but opposite chirality of the arrangement of the ligands around the Fe atoms.
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页码:2246 / 2249
页数:4
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