Catalysts Based on gamma-Al2O3-Supported Sulfated Zirconia for the Isomerization of Gasoline Fractions

被引：3

作者：

Smolikov, M. D. ^{[1
,2
]}

Bikmetova, L. I. ^{[1
]}

Kir'yanov, D. I. ^{[1
]}

Zatolokina, E. V. ^{[1
]}

Kazantsev, K. V. ^{[1
]}

Muromtsev, I. V. ^{[1
]}

Belyi, A. S. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Inst Hydrocarbon Proc, Omsk 644040, Russia

[2] Omsk State Tech Univ, Omsk 644050, Russia

来源：

CATALYSIS IN INDUSTRY | 2015年 / 7卷 / 01期

关键词：

sulfated zirconia; supported catalysts; n-hexane isomerization;

D O I：

10.1134/S2070050415010146

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Supported Pt/SZ/Al2O3 catalysts prepared via the thermolysis of zirconium sulfate in support pores are studied. The content of the active component (sulfated zirconia) in the catalysts is 25-30 wt %, 2-2.5 times lower than in massive catalysts equivalent in their catalytic characteristics. Tests in the isomerization of n-hexane are performed. It is shown that the total yields of 2,2- and 2,3-dimethylbutanes (DMB) on the supported catalysts at temperatures of 140-160 degrees C are 34-36 wt % at a stable C5+ catalyzate yield of 96-98 wt %, comparable to the results obtained on industrial isomerization catalysts based on sulfated zirconia. The results indicate that the supported Pt/SZ/Al2O3 catalysts can be used in the isomerization of C-5-C-6 fractions to synthesize environmentally friendly high-octane gasoline components.

引用

页码：24 / 29

页数：6

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