RECENT ADVANCES IN THE SYNTHESIS OF OPTICALLY-ACTIVE ALPHA-AMINO-ACIDS

被引：2
作者：
OGURA, K
INABA, T
机构：
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1991年 / 49卷 / 06期
关键词：
ALPHA-AMINO ACID; ASYMMETRIC SYNTHESIS; ALPHA-ALKYLATION OF GLYCINE; ALPHA-AMINATION OF CARBOXYLIC ACIDS; ALPHA-CARBOXYLATION OF AMINES;
D O I：
10.5059/yukigoseikyokaishi.49.575
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
To date, there have been explored many methods for synthesizing optically active alpha-amino acids. This review describes recent development of these synthetic method from a viewpoint of three types of asymmetric bond formation at the alpha-carbon of alpha-amino acis: (i) alpha-alkylation of glycine and its synthetic equivalents; (ii) alpha-amination of carboxylic acids; and (iii) alpha-carboxylation of amines.
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页码：575 / 583
页数：9
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