HYDROGENATION OF CINNAMALDEHYDE OVER RU/C CATALYSTS - EFFECT OF RU PARTICLE-SIZE

被引：156

作者：

GALVAGNO, S ^{[1
]}

CAPANNELLI, G ^{[1
]}

NERI, G ^{[1
]}

DONATO, A ^{[1
]}

PIETROPAOLO, R ^{[1
]}

机构：

[1] UNIV REGGIO CALABRIA,FAC INGN,I-89100 REGGIO CALABRIA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 64卷 / 02期

关键词：

D O I：

10.1016/0304-5102(91)85115-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogenation of cinnamaldehyde has been carried out over Ru catalysts supported on activated carbon at 333 K and atmospheric pressure using ethanol as solvent. The activity and selectivity of Ru/C catalysts have been investigated in order to elucidate the effect of metal particle size on the hydrogenation of unsaturated aldehydes. The specific activity expressed per Ru surface atom remains constant with metal dispersion, indicating that the rate-determining step of the reaction is structure-insensitive. Selectivity to cinnamyl alcohol increases with Ru particle size, reaching a value of about 60% on the less dispersed samples.

引用

页码：237 / 246

页数：10

共 20 条

[1]

[Anonymous], 1979, CATALYTIC HYDROGENAT

[2]

[Anonymous], 1975, STRUCTURE METALLIC C

[3]

FOUILLOUX P, 1988, HETEROGENEOUS CATALY, P123

[4] SELECTIVE HYDROGENATION OF ALPHA, BETA-UNSATURATED ALDEHYDES TO GIVE UNSATURATED ALCOHOLS OVER PLATINUM GERMANIUM CATALYSTS [J].

GALVAGNO, S ;

POLTARZEWSKI, Z ;

DONATO, A ;

NERI, G ;

PIETROPAOLO, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (23) :1729-1731

[5] HYDROGENATION OF CINNAMALDEHYDE OVER PLATINUM CATALYSTS - INFLUENCE OF ADDITION OF METAL CHLORIDES [J].

GALVAGNO, S ;

DONATO, A ;

NERI, G ;

PIETROPAOLO, R ;

PIETROPAOLO, D .

JOURNAL OF MOLECULAR CATALYSIS, 1989, 49 (02) :223-232

[6]

GARFUNKEL EL, 1986, SURF SCI, V102, P190

[7]

GIROIRFENDLER A, 1988, HETEROGENEOUS CATALY, P171

[8] ACTIVITY AND SELECTIVITY OF PT-FE/C ALLOYS FOR THE LIQUID-PHASE HYDROGENATION OF CINNAMALDEHYDE TO CINNAMYL ALCOHOL [J].

GOUPIL, D ;

FOUILLOUX, P ;

MAUREL, R .

REACTION KINETICS AND CATALYSIS LETTERS, 1987, 35 (1-2) :185-193

[9]

Millman W.S., 1977, CATALYSIS ORGANIC SY, P33

[10] SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES TO UNSATURATED ALCOHOLS OVER MIXED RUTHENIUM TIN BORIDE CATALYSTS [J].

NARASIMHAN, CS ;

DESHPANDE, VM ;

RAMNARAYAN, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (02) :99-100

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