CHLOROBIS(N-PHENYLSALICYLIDENEAMINATO-O,N)MANGANESE(III) - A MANGANESE SCHIFF-BASE COMPLEX DERIVED BY AN ELECTROCHEMICAL ROUTE

被引：16

作者：

MCAULIFFE, CA ^{[1
]}

PRITCHARD, RG ^{[1
]}

LUACES, L ^{[1
]}

GARCIAVAZQUEZ, JA ^{[1
]}

ROMERO, J ^{[1
]}

BERMEJO, MR ^{[1
]}

SOUSA, A ^{[1
]}

机构：

[1] UNIV SANTIAGO,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S010827019201120X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The five-coordinate manganese cation is sited at the centre of an approximate trigonal bipyramid. Distortions involving, primarily, the axial N atom [N-Mn-N 169.41(9), Cl-Mn-N 98.13(7), 91.57(8)-degrees] accommodate a ligand bite of less than 90-degrees [N-Mn-O 86.8(1), 86.5(1)-degrees] and a bulky equatorial Cl atom [Mn-Cl 2.235(1) angstrom.

引用

页码：587 / 589

页数：3

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