DIASTEREOSELECTIVE SYNTHESIS OF ENANTIOMERIC TERTIARY ALCOHOLS VIA NUCLEOPHILIC ADDITIONS TO PROTECTED D-ERYTHRULOSE AND L-ERYTHRULOSE DERIVATIVES

被引：16

作者：

CARDA, M

GONZALEZ, F

RODRIGUEZ, S

MARCO, JA ^{[1
]}

机构：

[1] UNIV JAUME 1,DEPT CIENCIAS EXPTL,E-12080 CASTELLON PLANA,SPAIN

[2] UNIV VALENCIA,FAC QUIM,DEPT QUIM ORGAN,E-46100 BURJASSOT,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)86047-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diastereoselectivity of the addition of several organometallic reagents to the carbonyl group of protected D- and L-erythrulose derivatives has been investigated. Tertiary alcohols are stereoselectively formed, the diastereomeric ratio being markedly dependent on the reagent type, solvent and temperature.

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页码：1511 / 1514

页数：4

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