O-DEMETHYLATION OF OPIOID DERIVATIVES WITH METHANE SULFONIC-ACID METHIONINE - APPLICATION TO THE SYNTHESIS OF NALOXONE AND ANALOGS

被引：17

作者：

ANDRE, JD

DORMOY, JR

HEYMES, A

机构：

[1] Sanofi-Chimie, Sisteron, cedex, Route de Gap

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 16期

关键词：

D O I：

10.1080/00397919208019086

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Naloxone 2 was obtained by demethylation of N-allylnoroxycodone 1 with methane sulfonic acid/methionine. This reagent is an excellent substitute for boron tribromide. It was used for the synthesis of analogous derivatives with variable results.

引用

页码：2313 / 2327

页数：15

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