Synthesis and Characterization of the Germathioacid Chloride Coordinated by an N-Heterocyclic Carbene

被引：2
|
作者：
Egawa, Yasunobu [1 ,3 ]
Fukumoto, Chihiro [1 ]
Mikami, Koichiro [2 ]
Takeda, Nobuhiro [1 ]
Unno, Masafumi [1 ]
机构：
[1] Gunma Univ, Dept Chem & Chem Biol, Grad Sch Sci & Technol, Kiryu, Gunma 3768515, Japan
[2] Sagami Chem Res Inst, Funct Polymer Grp, 2743-1 Hayakawa, Ayase, Kanagawa 2521193, Japan
[3] Japan Agcy Marine Earth Sci & Technol JAMSTEC, Frontier Res Grp, Res & Dev R&D Ctr Marine Biosci, 2-15 Natsushima Cho, Yokosuka, Kanagawa 2370061, Japan
来源：
INORGANICS | 2018年 / 6卷 / 03期
基金：
日本学术振兴会;
关键词：
germanium; germanethione; germathioacid chloride; N-heterocyclic carbines;
D O I：
10.3390/inorganics6030076
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Carboxylic acid chlorides are useful substrates in organic chemistry. Many germanium analogues of carboxylic acid chloride have been synthesized so far. Nevertheless, all of the reported germathioacid chlorides use bidentate nitrogen ligands and contain germanium-nitrogen bonds. Our group synthesized germathioacid chloride, Ge(S)Cl{C6H3-2,6-Tip(2)}(Im-i-Pr2Me2), using N-heterocyclic carbene (Im-i-Pr2Me2). As a result of density functional theory (DFT) calculation, it was found that electrons are localized on sulfur, and the germanium-sulfur bond is a single bond with a slight double bond property.
引用
收藏
页数：8
相关论文
共 50 条
  • [1] N-heterocyclic carbene coordinated gallanes and chlorogallanes
    Cole, Marcus L.
    Furfari, Samantha K.
    Kloth, Marc
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (18) : 2934 - 2940
  • [2] Synthesis of N-heterocyclic carbene boranes via silver N-heterocyclic carbene complexes
    Ono, Shintaro
    Watanabe, Takashi
    Nakamura, Yosuke
    Sato, Hiroyasu
    Hashimoto, Toru
    Yamaguchi, Yoshitaka
    POLYHEDRON, 2017, 137 : 296 - 305
  • [3] Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene
    P. A. Petrov
    E. A. Golubitskaya
    N. B. Kompankov
    I. V. Eltsov
    T. S. Sukhikh
    M. N. Sokolov
    Journal of Structural Chemistry, 2019, 60 : 1989 - 1994
  • [4] Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene
    Petrov, P. A.
    Golubitskaya, E. A.
    Kompankov, N. B.
    Eltsov, I. V.
    Sukhikh, T. S.
    Sokolov, M. N.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 60 (12) : 1989 - 1994
  • [5] N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters
    Shen, Hui
    Tian, Guolong
    Xu, Zhen
    Wang, Lingzheng
    Wu, Qingyuan
    Zhang, Yuhao
    Teo, Boon K.
    Zheng, Nanfeng
    COORDINATION CHEMISTRY REVIEWS, 2022, 458
  • [6] Synthesis and Reactivity of N-Heterocyclic Carbene Coordinated Formal Germanimidoyl-Phosphinidenes
    Chen, Haonan
    Chen, Yizhen
    Li, Tong
    Wang, Dongmin
    Xu, Lei
    Tan, Gengwen
    INORGANIC CHEMISTRY, 2023, 62 (51) : 20906 - 20912
  • [7] Synthesis and characterization of N-heterocyclic carbene complexes of uranium(III)
    Nakai, H
    Hu, XL
    Zakharov, LN
    Rheingold, AL
    Meyer, K
    INORGANIC CHEMISTRY, 2004, 43 (03) : 855 - 857
  • [8] Synthesis and characterization of palladacyclopentadiene complexes with N-heterocyclic carbene ligands
    Canovese, Luciano
    Santo, Claudio
    Scattolin, Thomas
    Visentin, Fabiano
    Bertolasi, Valerio
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 794 : 288 - 300
  • [9] Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene:: versatile synthons for synthesis of N-heterocyclic carbene complexes
    Yamaguchi, Y
    Kashiwabara, T
    Ogata, K
    Miura, Y
    Nakamura, Y
    Kobayashi, K
    Ito, T
    CHEMICAL COMMUNICATIONS, 2004, (19) : 2160 - 2161
  • [10] Synthesis of Cationic N-Heterocyclic Carbene Lanthanide Bromide and the Influence of N-Heterocyclic Carbene and Lanthanide Metals
    Yao, Haisheng
    Zhang, Jinguo
    Zhang, Yong
    Sun, Hongmei
    Shen, Qi
    ORGANOMETALLICS, 2010, 29 (22) : 5841 - 5846
12345