THERMAL MICHAEL REACTION .2. MANNICH BASE STRUCTURE

被引：18

作者：

BUCHANAN, GL

CURRAN, ACW

WALL, RT

机构：

[1] Chemistry Department, The University, Glasgow

来源：

TETRAHEDRON | 1969年 / 25卷 / 22期

关键词：

D O I：

10.1016/S0040-4020(01)83052-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The structures of a number of Mannich bases have been checked by NMR, the deshielding effect of N-protonation being used to identify adjacent protons. Whilst Mannich bases lacking a β-proton can react Michael-wise via a rearrangement, their quaternary methiodides do not. On this evidence, anomalous literature reports can be rationalised. © 1969.

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页码：5503 / &

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