TRIAD SEQUENCE ASSIGNMENT OF THE C-13-NMR SPECTRA OF COPOLYMERS OF ETHYLENE-OXIDE AND 1,2-BUTYLENE OXIDE

被引：71

作者：

HEATLEY, F

YU, GE

SUN, WB

PYWELL, EJ

MOBBS, RH

BOOTH, C

机构：

[1] Department of Chemistry, University of Manchester, Manchester

来源：

EUROPEAN POLYMER JOURNAL | 1990年 / 26卷 / 05期

基金：

英国惠康基金;

关键词：

D O I：

10.1016/0014-3057(90)90213-N

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

13C-NMR spectra of homopolymers and block and statistical copolymers of ethylene oxide and 1,2-butylene oxide have been studied in CDCl3 and C6D6 solution at 75.5 MHz with the aid of resolution-enhancement and subspectrum editing techniques. Resonances from triad sequences, endgroups, initiation sites and inverted monomer addition have been identified in C6D6 solution. The assignments have been tested for consistency using necessary statistical relationships, and have been shown to conform to a simple chemical shift additivity scheme. © 1990.

引用

页码：583 / 592

页数：10

共 7 条

[1]

DODDRELL DM, 1982, J CHEM PHYS, V77, P2745

[2] RESOLUTION ENHANCEMENT IN FT NMR THROUGH USE OF A DOUBLE EXPONENTIAL FUNCTION [J].